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Liverpool have been drawn against Paris Saint-Germain in the last 16 of the Champions League, after topping their group with seven wins from eight matches.
Arsenal will face PSV Eindhoven, who knocked out Juventus in the knockout play-off.
Aston Villa, who secured the final automatic spot, will meet Belgian side Club Brugge, the same team that handed them one of their two defeats in the group stage.
The first legs of the last 16 will be held on 4 and 5 March, with return legs on 11 and 12 March.
Liverpool and PSG previously met in the 2018-19 group phase, when Liverpool went on to win the Champions League for the sixth time.
Their first encounter was in the 1997 European Cup Winners’ Cup semi-finals, where PSG triumphed 3-2 on aggregate before losing to Barcelona in the final.
If both Liverpool and Villa win their ties, they will meet in the quarter-finals.
Arsenal will face the winner of the Madrid derby between Real Madrid and Atletico Madrid in the quarter-finals if they beat PSV.
Other clashes include Bayern Munich facing Bayer Leverkusen, Barcelona taking on Benfica, Feyenoord facing Inter Milan, and Borussia Dortmund playing Lille.